pH | [H+] | pOH | [ | Acidic or basic |
| | | 6.25 x 10-9 | |
| | 7.52 | | |
| 0.0035 | | | |
0.5 | | | | |
Labels: Chemical Equilibrium, Exam Help
Labels: Chemistry Lecture, Exam Help
III. Content:
Write the expression for Kc and Kp if applicable, for the following reversible reactions at equilibrium:
1. HF(aq) + H2O (l) <--------> H3O + (aq) + F- (aq)
2. 2 NO(q) + O2 (g) <--------> 2 NO2 (q)
3. 2HgO(s) <--------> 2Hg(l) + O2(g)
4. H2SO3(aq) + H2O(l) <--------> H3O+(aq) + HSO3 (aq)
5. H2(g) + I2(g) <--------> 2HI(g)
III. Content:
1. Consider the following heterogeneous equilibrium:
CaCO3 (s) <--------> CaO (s) + CO2 (g)
At 800 oC, the pressure of CO2 is 0.236 atm. Calculate (a) Kc and (b) Kp for the reaction at
this temperature.
2. The equilibrium constant Kp for the reaction
2 NO2 (g) --------> 2 NO (g) + O2(g)
is 158 at 1000 K. Calculate PO2 if PNO2 = 0.400 atm and PNO = 0.270 atm.
II. Solve the following problems:
1. The equilibrium constant Kp for the reaction
2 NO2 (g) <--------> 2 NO (g) + O2(g)
is 158 at 1000 K. Calculate PO2 if PNO2 = 0.400 atm and and PNO = 0.270 atm.
2. At equilibrium a 1.0 L vessel contains 20.0 mol of H2, 18.0 mol of CO2, 12.0 mol of H2O, and 5.9 mol of CO
at 427°C.What is the value of Kc at this temperature for the following reaction?
CO2(g) + H2(g)<-------->CO(g) + H2O(g)
3. In the reaction: cis-stilbene<-------->trans-stilbene.
The equilibrium constant for this system is 24 at 200 oC. Suppose that initially only cis-stilbene is present at a
concentration of 0.850 mol/L. Calculate the concentrations of these species at equilibrium.
III. Predict the equilibrium shift in the following:
H2 (g) + I2 (g) <--------> 2 HI (g) (change in H > 0)
III. Content:
I. Identification: Identify the term being described in each of the following statements. Choose the letter of the correct answer on the box below. Use capital letters.
_____ 1. Compounds containing Hydrogen that ionize to yield H+
_____2. Compounds containing Hydrogen that ionize to yield OH-
_____3. An acid that contains 2 ionizable Hydrogen.
_____4. A particle that remains when an acid has donated a Hydrogen ion.
_____5. A substance that can act as both an acid and base.
A. Acid B. Ampoteric C. Base D. Conjugate base E. Conjugate acid F. Monoprotic G. Diprotic
II. Label the Bronsted-Lowry acid and base in the following:
1. H2SO4 + OH <--------> HSO4 - + H2O
2. NH3 + H2O <--------> NH4 + + OH –
3. HSO4 - + H2O <--------> SO4 -2 + H3O +
IV. Answer:
Direction: Solve the following problems.
Show your solution.
1. Calculate the pH
a. H+ = 1.3 x 10 -5
b. H+ = 5.2 x 10 -7
2. Calculate the pOH
a. OH-= 5.3 x 10 -10
b. OH-= 8.9 x 10 -9
3. Calculate the H+
a. OH-= 8.3 x 10 -5
4. Calculate the OH-
a. H+ =9.3 x 10 -5
5. Calculate the H+
a. pH= 3.2
6. Calculate the pH
a. OH-= 3.63 x 10 -6
7. Calculate the pOH
a. pH= 10
8. Calculate the pH
a. 0.76 M KOH
Identify the term/ person/concept being described in each of the following statements/questions.
1. What does pH stands for?
2. Why do we need to compute the Ka value of a weak acid?
3. What does it mean by the higher Ka value?
4. It is a substance that completely dissociate in water, forming H+ and an anion.
5. It is a substance that partially dissociate in water, forming H+ and an anion.
6-9. how do we determine the acid strength of a given weak acid.
10. Who formulated the pH concept?
II. Problem Solving. Answer the following problem carefully. Show your solution.
1. A 0.085 M aqueous solution of a weak, monoprotic acid is 0.85% ionized. Calculate the Ka.
2. The pH of a 0.35 M solution uric acid is 2.17. What is the value of Ka?
III. Answer the following problem carefully. Show your solution.
Give the pH at each point when 100 mL of 0.10 M HCl is titrated with 0.10 M NaOH
a. 0.00 Ml NaOH b. 20 ml NaOH c. 50 mL NaOH d. 100 mL NaOH e. 110 mL
I. True or False: Write T if the statement is True and F if the statement is False.
_____1. When the concentration of the components is changed, K also changes.
_____ 2. The concept of H+ was introduced by Arrhenius.
_____ 3. Equilibrium constant is the ratio of the amount of products to the amount of the reactants at
equilibrium.
_____ 4. The endpoint is reached when the color of the indicator in titration changes.
_____ 5. Catalysis only affects the rate of reaction.
_____ 6. Baling soda and bleach are acidic; vinegar and orange juice are basic.
_____ 7. Sweating of humans to release body heat is a way of achieving equilibrium.
_____ 8. K of an aqueous solution can be expressed in terms of Kp.
_____ 9. A rise in the curve indicates that the titrant is a base while a decline shows that the titrant is an acid.
_____ 10. Strong bases dissociate completely into the cation and OH-.
____ 11. The counting unit in chemistry
____12. It describes the behavior of gases
____13. It is the collision of the molecules of the gases with the conatiner.
____14. it is the result of the molecules collision with one another.
____15. Measurement that deals with the heat changes in the reaction.
____16. quantitative relationships of the reactants and products in a balanced chemical reaction
II. Problem Solving (14 pts.)
1. Given : 2 NO2 (brown ) N2O4 (colorless). What is the color to be seen in the reaction if :
(for a-c)
a. NO2 was added
b. NO2 was removed
c. catalyst was added
d. Give the equilibrium constant
e. What is the equilibrium constant (K) if [NO2] = 0.05 M, [N2O4] = 1.0 x 10 -5 M at
equilibrium
f. If NO2 = 0.025 M initially and K = 0.0625. What is the concentration of each species at
equilibrium?
2. Complete the table.(2 pts each)
pH | H+ | pOH | OH- | Acidic/ Basic |
(1) | (2) | (3) | 6.25 x 10 -9 | (4) |
(5) | (6) | 7.52 | (7) | (8) |
(9) | 0.0035 | (10) | (11) | (12) |
0.5 | (13) | (14) | (15) | (16) |
3. Give the pH at each point. A 32 ml of a 0.05 M HCl was titrated with a 0.011 M NaOH.( 5 pts. each pH)
a. analyte
b. titrant
c. 0.00 mL
d. 62.60 mL
e. 145.45 mL
f. 155.34 mL
Labels: Chemistry Lecture